On the space of Hermitian matrices measure is defined as a product of all the degrees of freedom of the Hermitian matrix
Last line is due to
Overall factor will be absorbed by normalization of any average anyway so from now on you can forget it even existed. Every matrix in is in one-to-one correspondence with the vector
Elements of as a vector can be referred to with a help of double index notation . The inner product on this vector space is as always
so it is actually
Unitary conjugation leaves this inner product unchanged
so it's an orthogonal transformation in . Any orthogonal map in has . Since is connected to the identity, . The bottom line is that Jacobian of coordinate transformation is 1.